Order sp_who2, after database with this commands:

declare @tempTable table (SPID INT,Status VARCHAR(255),
Login VARCHAR(255),HostName VARCHAR(255),
BlkBy VARCHAR(255),DBName VARCHAR(255),
Command VARCHAR(255),CPUTime INT,
DiskIO INT,LastBatch VARCHAR(255),
ProgramName VARCHAR(255),SPID2 INT,
REQUESTID INT);

 INSERT INTO @tempTable
EXEC sp_who2 

select *
from @tempTable order by DBName